The NMS is Canada's master library of pre-written construction specification sections. Every procedure, product, and method an architect is likely to encounter on a Canadian project has a corresponding NMS section, organized by MasterFormat. Knowing the NMS means knowing how the specification system works, not what any one section says verbatim.
Sub-objective 8.5.1 asks candidates to explain the connection between the MasterFormat and the National Master Specification. That tells you what the exam expects: a working knowledge of how the NMS is organized and what each Division covers, not word-for-word spec memorization.
The NMS also provides the vocabulary that shows up across Section 3 and Section 4 questions: MasterFormat Division numbers, the three-part section format, submittals, and substitutions. Familiarity with even a handful of NMS sections builds that vocabulary in context.